Suzuki-Miyaura Coupling with Quasi-Heterogeneous Palladium
Advanced Synthesis & Catalysis, 345(8), 931- 935, August 2003
John R. Sowa Jr., Ph.D. Department of Chemistry and Biochemistry
D.A. Conlon, B. Pipik, S. Ferdinand, C.R. LeBlond, B. Izzo, G.J. Ho, J.M. Williams, Y.J. Shi & Y. Sun
The Suzuki–Miyaura cross-coupling reaction using heterogeneous Pd/C has a homogeneous component. The soluble palladium concentration increases during the reaction reaching a maximum at ca. 90% conversion before falling to <4 ppm.